Reaction of imidazole derivatives with 2,3-di(bromomethyl)pyrazine results in the formation of the new pyrazine-bridged diimidazolium salts 1–8. These salts proved to be valuable precursors for dinuclear complexes with mixed NHC/pyrazine ligands. Two of the pyrazine-bridged diimidazolium salts 3·H 2 O and 8·2H 2 O have been characterized by X-ray diffraction. Furthermore, the first catalytic studies with mixtures of palladium acetate and the imidazolium salts have been carried out. The in situ prepared palladium complexes derived from the diimidazolium salts 1–8 exhibit a modest catalytic activity in Heck-type coupling reactions between 4-bromo benzaldehyde and styrene or n-butyl acrylate.