A new method of thermoluminescent (TL) measurement of radiation doses ranging from micrograys up to a megagray has been recently developed at IFJ. This method is based on a newly discovered behavior of LiF:Mg,Cu,P detectors at doses exceeding 1 kGy. Significant changes in their glow-curves are observed at higher doses; of special importance is occurrence of a new, well separated peak for doses above 50 kGy, thus these detectors can be used for measurements of doses at ultra-high dose range. In order to check the glow-curve features in the high dose region for different types of LiF:Mg,Cu,P and LiF:Mg,Ti detectors after irradiation with heavy charged particles, tests at the 24 GeV/c proton beam of IRRAD1 irradiation zone at the CERN Proton Synchrotron accelerator up to 1 MGy were performed. The occurrence of the high dose peak in the glow-curve of LiF:Mg,Cu,P detectors resulting from heavy particles irradiation was confirmed. Results of this investigation are presented in this paper.