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All regioisomeric di- and tetrahydrogeranylgeraniols possessing the C2C3 double bond were prepared as authentic samples. The synthetic C20-isoprenoid alcohols were separated well by gas chromatography. Based on the chromatographic analysis, the enzymatic reduction pathway of a geranylgeranyl group was investigated to identify the last stage of (bacterio)chlorophyll biosynthesis in phototrophs. The...
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