The kinetics of structural transformations of the Fe 75 Ni 2 Si 8 B 13 C 2 amorphous alloy under non-isothermal conditions was studied. It was shown that the amorphous alloy was stable up to 723K, when multi-step structural transformations start, involving formation of stable α-Fe(Si) and Fe 2 B crystalline phases, and a metastable Fe 15 Si 3 B 2 phase, their growth and the decomposition of the metastable phase into the two stable phases. Peakfit software was used to resolve the overlapping peaks corresponding to different crystallization steps, at different heating rates. The kinetic parameters corresponding to each of the steps were evaluated and kinetic triplet for every single step was established (g(α)=[−ln(1−α)] 1/3 , E a =375.1±0.8kJ/mol and lnA=56.2±1.0 for step 1; E a =341.6±0.5kJ/mol and lnA=49.3±0.5 for step 2). The effects of structural transformations on the established kinetic model were discussed in detail.