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Rovibrational manifolds in low frequency intermolecular vibrations of prototypical hydrogen-bonded interactions OC–HX (X=F, Cl, CN) are reported using a near infrared quantum cascade cw supersonic jet spectrometer. (i) OC–HCl is studied to evaluate future capabilities of the QCL spectrometer. (ii) Analysis of OC–HF demonstrates applicability to vibrations greater than 80cm −1 above the ground...
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