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Adsorption isotherms have been computed by Monte-Carlo simulation for methane/carbon dioxide and ethane/carbon dioxide mixtures adsorbed in the zeolite silicalite. These isotherms show remarkable differences with the ethane/carbon dioxide mixtures displaying strong adsorption preference reversal at high coverage. To explain the differences in the Monte-Carlo mixture isotherms an exact matrix calculation...
The influence of Förster resonance energy transfer (FRET) on temporal and polarization characteristics of donor fluorescence was theoretically investigated (by means of Monte-Carlo calculations) in a donor–acceptor solid solution, where acceptor molecules are characterized by the high probability of intersystem crossing (ISC) S 1 →T 1 . It was shown that parameters of the donor fluorescence...
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