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The vibronic coupling constants and transition dipole moments for the Franck–Condon and adiabatic S 1 states of anthracene, 9-chloroanthracene, and 9,10-dichloroanthracene were calculated and analyzed by using the concept of vibronic coupling density (VCD). The transition dipole moments are also analyzed on the basis of the transition dipole moment density (TDMD). The VCD analyses indicate...
To investigate the influence of amine structure on the internal conversion from S2 to S1, three aliphatic amines containing the same number of degrees of freedom, but with different degree of N-substitution, were investigated with femtosecond time-resolved mass spectrometry. As N-substituents lower the excitation energies, and the excitation in all cases is by a 200nm photon, the S1 density-of-states...
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