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The dipole moment and polarizability changes have been determined from electroabsorption (EA) spectroscopy of solid films of fac tris(2-(phenyl)pyridinato,N,C 2' )iridium (III) [Ir(ppy) 3 ]. The maximum changes in the dipole moment |Δμ| S =(5.0+/-0.5) D/f (f is the local field correction factor: 1.3-1.7) accompany ground state to the lowest singlet, and |Δμ| T ...
Electric-field modulated absorption spectra in the range 270–580 nm have been studied in solid films of Pt(II)octaethylporphyrin (PtOEP) formed by vapour deposition onto room-temperature quartz substrates. The electroabsorption (EA) spectra were measured at first (1ω) and second (2ω) harmonic of fundamental frequency of modulating field (ω) applied to the sample in a sandwich cell arrangement with...
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