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The microwave spectrum of cyclohexylisocyanate, c–C 6 H 11 NCO, has been investigated from 10,000 to 21,000MHz and 44 transitions for the more stable equatorial-trans conformer were assigned. The rotational constants of the ground vibrational state were determined: A=3546.87(28), B=936.12(1) and C=839.06 (1)MHz. With these rotational constants and ab initio MP2(full)/6-311+G(d,p) predicted...
The ortho-positronium (o-Ps) lifetime and intensity in cyclohexane was measured as a function of temperature at various wavelengths of illuminating light. Accommodation of excess electrons in traps was observed in whole range of rigid crystalline phase; the trap depth was about 0.75eV.At the wavelength λ<880nm a slight decrease of o-Ps lifetime in rigid phase was observed, which could be explained...
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