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This work presents an experimental and theoretical investigation about the influence of the dopant in the electropolymerization of α-tetrathiophene. Adherent, insoluble, and black polymeric films were obtained in the presence of LiClO 4 , while no evidence about the formation of polymer was detected with LiCl and LiBr electrolytes. On the other hand, quantum mechanical calculations based on...
The generation of excited triplet luminophor by recombination of electrochemically injected ions is calculated. The reversibility of triplet production is shown to affect insignificantly the triplet accumulation and their quantum yield. The free energy dependence of the latter is specified and fitted to the available experimental data.The maximal quantum yield of triplet luminescence found experimentally...
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