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Anisotropic double exchange interaction is considered for the valence-delocalized [Fe 2.5+ Fe 2.5+ ] cluster with strong Anderson–Hasegawa double exchange (DE) coupling. The combined effect of spin–orbit interaction and DE between the excited states of the mixed-valence Fe ions results in the inter-ion anisotropic DE coupling. The coefficients of anisotropic DE coupling are linearly...
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