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The search for highly active catalysts with low-Pt content to advance the commercialization of fuel cells is continuing to receive ample attention. Herein, we report that by doping a single Pt atom into Au25 to form Pt1Au24 nanoclusters, the electrocatalytic activity for the direct formic acid oxidation (FAO) to carbon dioxide is enhanced significantly. The mass activity of Pt1Au24 (3.7 A mgPt+Au−...
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