The carbides present after creep testing a 9Cr–1Mo steel at 566 °C over a range of stress levels giving rupture times of up to 7300 h have been characterized and identified using a transmission electron microscopy, energy-dispersive X-ray spectroscopy and electron diffraction. The initial carbide precipitates present were M 7 C 3, (NbV)C and VC and it was determined that M 6 C carbide precipitates were present in all specimens after elevated temperature exposure for greater than approximately 1700 h. No precipitation of M 23 C 6 was detected. The evolutionary sequence from the initially present carbides during high temperature exposure involved the formation of the stable M 6 C carbide directly, without the intermediate formation of M 23 C 6 , as is reported to occur in other Cr–Mo steels.