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The results are reported of a selected ion flow tube (SIFT) study of the rate coefficients and the ionic products of the reactions of H 3 O + , NO + and O +2 with some 11 aldehydes and nine ketones including the structural isomers of some. We assume that the 20 exothermic H 3 O + proton transfer reactions proceed at the collisional rate and on...
We report the results of a selected ion flow tube (SIFT) study of the reactions of H 3 O + , NO + and O +2 with some 17 alcohols ranging in complexity from methanol to octanol and menthol, and including some structural isomers. This study was carried out in order to extend the database (i.e. rate coefficients and product ions of appropriate ion/molecule reactions)...
We report the results of a selected ion flow tube (SIFT) study of the reactions of H 3 O + , NO + and O +2 with some 10 ethers, M. We assume that all the exothermic proton transfer reactions of H 3 O + with all the ether molecules occur at the collision rate, i.e. the rate coefficients, k, are equal to k c , then it is seen that the k for...
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