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Electron attachment to the haloacetonitriles FCH 2 CN, ClCH 2 CN, and BrCH 2 CN have been studied over the temperature range 295-556 K, using a flowing-afterglow Langmuir-probe apparatus. No attachment is observed for FCH 2 CN; dissociative electron attachment to FCH 2 CN is presumably endothermic. Electron attachment to ClCH 2 CN produces only Cl...
A flowing-afterglow Langmuir-probe apparatus was used to measure rate constants (k a ) for electron attachment to NF 3 and PF 5 over the temperature range T = 300-550 K. Electron attachment to NF 3 is dissociative and produces only F - ionic product in the temperature range studied. At room temperature, k a (NF 3 ) = 7 ± 4 10 -1...
Dissociative electron attachment to CCl 3 Br has been studied using a flowing afterglow/Langmuir probe (FALP) and a crossed beam technique. In the FALP experiment the overall attachment rate coefficients and the branching ratio into the Cl - and the Br - product channels, R = Cl - /(Cl - + Br - ), were measured as a function of the gas temperature,...
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