The abatement of NO with CH 4 in the presence of O 2 was studied on Mn-ZSM5 (Mn percent exchange 2 to 75%), prepared from Na-ZSM5 by the ion-exchange method. Samples were characterised by FTIR, ESR and magnetic measurements. Both ESR and magnetic measurements showed that all manganese was present as Mn I I . FTIR showed the formation of carbonyls (one type only, on manganese equivalent sites). The intensity of bands from carbonyls was almost proportional to the manganese content.The selectivity for NO abatement, reaction orders in O 2 , NO or CH 4 , and apparent activation energy were independent of the manganese content, suggesting that the same surface complexes were formed on all Mn-ZSM5 catalysts. On Mn-ZSM5, turnover frequencies (molecules s - 1 Mn-atom - 1 ) for both NO abatement and CH 4 reaction were nearly independent of the manganese content and close to the relevant values on Co-ZSM5 (previously investigated in our laboratory), but substantially higher than those on Cu-ZSM5 (Cu percent exchange 98%, studied for a comparison). On Mn-ZSM5, Co-ZSM5 and Cu-ZSM5, the adsorption at RT of NO+O 2 or NO 2 caused the formation of nitrates. The normalised intensity (per atom) of monodentate nitrate bands (~1520 and ~1320 cm - 1 ) was (i) independent of the metal content, (ii) the same in Mn-ZSM5 and Co-ZSM5, and (iii) much higher in Mn-ZSM5 and Co-ZSM5 than in Cu-ZSM5. On all these catalysts, NO abatement rates were proportional to the concentration of these monodentate nitrates. On FTIR evidence, these species reacted with methane at the same temperature at which the various catalysts were active. These findings suggest a role of monodentate nitrates in the SCR reaction.