A new hybrid material [Zn 3 O 3 (C 13 H 14 N 2 ) 3 ]V 6 O 15 (1) with extended framework structure has been synthesized hydrothermally and characterized by vibrational spectroscopy, thermogravimetry and complete single crystal X-ray diffraction analysis. The compound has a complex three-dimensional covalent framework structure. It exhibits a fully oxidized novel oxometallic framework containing 10-membered {V 4 ZnO 5 } oxometalate rings and 4,4′-trimethylene dipyridine ligands (C 13 H 14 N 2 ) that connect pairs of crystallographically equivalent zinc atoms. The extended structure of 1 may also be viewed as containing a framework of corner-sharing {VO 4 } and {ZnO 2 N 2 } polyhedra together with 4,4’-trimethylene dipyridine ligands linking zinc centers. The hybrid material is thermally stable up to 323°C. It contains metal centers and coordination geometry that make it a potentially attractive model compound for investigating the structures of metallo-organic biomolecules by use of solid state NMR spectroscopic techniques. Crystal data for C 39 H 42 N 6 O 18 V 6 Zn 3 : monoclinicic P2 1 , a=10.9894(9)Å, b=18.1493 (15)Å, c=13.0903 (11)Å, β=109.8880(10)°, V=2455.1(4)Å 3 , Z=2, D calc. =1.873Mg/m 3 .