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An investigation of the coating structure formed on Mg–3wt.%Al–1wt.%Zn alloy sample subjected to plasma electrolytic oxidation was examined by field-emission transmission electron microscopy. The plasma electrolytic oxidation process was conducted in a phosphoric acid electrolyte containing K2ZrF6 for 600s. Microstructural observations showed that the coating consisting of MgO, MgF2, and ZrO2 phases...
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