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Vapor deposited thin films of various calix[n]arenes have been investigated by contact mode atomic force microscopy. Two classes of thin films have been defined. For para-H-calix-4-arene, para-H-calix-6-arene, and para-iso-propyl-calix-4-arene pre-organized structures are observed on deposition. For para-iso-propyl-calix-6-arene, para-tert-butyl-calix-4-arene, para-tert-butyl-calix-6-arene, para-tert-butyl-calix-8-arene...
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