Binuclear compounds of the type [Pd(μ-L)(N3)(PPh3)]2 {L=pyrazolate (1); 3,5-dimethylpyrazolate (2); 4-iodopyrazolate (3); PPh3=triphenylphosphine} were synthesized and characterized by elemental analyses, infrared and 1H and 31P{1H} NMR spectroscopies. The crystal and molecular structures of the complex [Pd(μ-dmPz)(N3)(PPh3)]2 (2) were determined by single-crystal X-ray diffraction techniques. In vitro antimycobacterial evaluation demonstrated that compound [Pd(μ-Pz)(N3)(PPh3)]2 (1) displayed a MIC of 8.16μM, being more active than some commonly used anti-TB drugs and other Pd(II) complexes.