Light sources with lower color temperature (CT) show markedly less suppression effect on the secretion of melatonin, an oncostatic hormone. Light sources with higher color rendering index (CRI) provide better visual comfort. In this report, we demonstrate the design and fabrication of low CT, high CRI fluorescent organic light-emitting diode (OLED) with five-band emitting from a single emissive layer. The best performed device exhibits a CT of 1773K, much lower than that of candles (1800–2000K) or incandescent bulbs (2000–2500K), 87 CRI, a beyond theoretical limit external quantum efficiency (EQE) 6.4%, and 11.9lm/W at 100cd/m 2 . One major reason for having the ultra-low CT and relative high CRI may be attributed to the significantly intensive deep red emission. The comparatively high efficacy and EQE may be attributed to the employment of a smooth stepwise energy-level structure, enabling low injection barriers and balance carrier injection.