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The addition of β-dioxygenato compounds to methyl vinyl ketone was catalysed by nickel(II) and cobalt(II) complexes with the polymerizable β-ketoesterato 2-(acetoacetoxy) ethyl methacrylate (AAEMA - ) under homogeneous and heterogeneous phases. The homogeneous reactions were carried out using the soluble Ni(AAEMA) 2 and Co(AAEMA) 2 complexes whereas the heterogeneous catalytic tests were carried out using the copolymers obtained by reaction of M(AAEMA) 2 (M = Ni or Co) with suitable acrylamides.
Centro di studi CNR sulle Metodologie Innovative in Sintesi Organiche MISO, Istituro di Chimica del Politecnico di Bari, trav. 200 Re David 4I-70126 BariItaly
Centro di studi CNR sulle Metodologie Innovative in Sintesi Organiche MISO, Istituro di Chimica del Politecnico di Bari, trav. 200 Re David 4I-70126 BariItaly
Centro di studi CNR sulle Metodologie Innovative in Sintesi Organiche MISO, Istituro di Chimica del Politecnico di Bari, trav. 200 Re David 4I-70126 BariItaly