Conducting polypyrrole (PPy) films doped with p-toluenesulfonate (TOS − ), ClO 4 − , and Cl − were electrochemically prepared, respectively. The electrochemical capacitance properties of the PPy films were investigated with cyclic voltammetry (CV), galvanostatical charge/discharge, and electrochemical impedance spectroscope (EIS) techniques. The morphology observation and structure analysis of PPy films were performed by scanning electron microscope (SEM) and X-ray diffraction (XRD). The results showed that PPy-Cl and PPy-TOS were characterized with a highly porous and ordered structure, which led to their fast ion switch processes. Moreover, they exhibited a rectangle-like shape of voltammetry characteristics even at a scanning rate of 50 mV·s −1 , a linear variation of the voltage with respect to time in the charge/discharge process, and almost ideal capacitance behavior in low frequency, even in deeply charged/discharged states in 1 mol·L −1 KCl solution. Furthermore, specific capacitance of PPy-Cl (polymerization charge of 2 mAh·cm −2 ) could reach 270 F·g −1 (scanning rate of 5 mV·s −1 ) or 175 F·g −1 (scanning rate of 200 mV·s −1 ) and its specific energy could reach 35.3 mWh·g −1 . Moreover, with heavier doping ion (TOS − ), PPy-TOS (polymerization charge of 2 mAh·cm −2 ) had a slightly smaller specific capacitance (146 F·g −1 , scanning rate of 5 mV·s −1 ), but a very rapidly charge/discharge ability (specific capacitance of 123.6 F·g −1 at scanning rate of 200 mV·s −1 ) and its specific power could reach 10 W·g −1 . In addition, both PPy-TOS and PPy-Cl had good cycleability. All of the above implied that the PPy-Cl and PPy-TOS were two kinds of promising electrode material for supercapacitors.