Nano-sized Li 2 TiO 3 powder was fabricated by an organic–inorganic solution route. A steric entrapment route employing ethylene glycol was used for the preparation of the nano-sized Li 2 TiO 3 particles. Titanium isopropoxide and lithium nitrate were dissolved in liquid-type ethylene glycol without any precipitation. With the optimum amount of the polymer, the metal cations (Li and Ti) were dispersed in the solution and a homogeneous polymeric network was formed. The organic–inorganic precursor gels were turned to crystalline powders through an oxidation reaction during a calcination process. The dried precursor gel showed the carbon-free Li 2 TiO 3 crystalline form which was observed above 400°C. The primary particle size of the carbon-free Li 2 TiO 3 was about 70nm, and the structure of the crystallized powder was porous and agglomerated. The powder compact was densified to 92% of TD at a relatively low sintering temperature of 1100°C for 2h.