The linear transformation group approach is developed to simulate heat diffusion problems in a media with the thermal conductivity and the heat capacity are nonlinear and obeyed a striking power law relation, subject to nonlinear boundary conditions due to radiation exchange at the interface according to the fourth power law. The application of a one-parameter transformation group reduces the number of independent variables by one so that the governing partial differential equation with the boundary conditions reduces to an ordinary differential equation with appropriate corresponding conditions. The Runge–Kutta shooting method is used to solve the nonlinear ordinary differential equation. Different parametric studies are worked out and plotted to study the effect of heat transfer coefficient, density and radiation number on the surface temperature.