In-situ time-dependent Raman spectra were measured on the thermal annealing of diamond-like carbon films produced by Pulsed Laser Deposition (PLD-DLC), with or without the presence of atomic hydrogen etching. It was found that annealing transformed DLC films into a graphitic structure in both cases and this transformation was completed within 30 min of annealing. Atomic hydrogen etches away the G*=1500 cm - 1 band, revealing the existence of the D*=1200 cm - 1 band. Both G*- and D*- phases are as stable as graphite during thermal annealing. These observations separate the effects of thermal annealing and annealing with atomic hydrogen etching on diamond-like carbon films.