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Three, 2,5-diphenyl-1,3,4-thiadiazole-containing vinyl monomers and their polymers were synthesized and the HOMO and LUMO energies of the compounds, as estimated from cyclic voltammetry data, were −6.35 to −6.14eV and −3.02 to −2.84eV, respectively. The optical band gaps (E g ) were similar to those determined from cyclic voltammograms. The fluorescent emission spectra of all monomers and polymers displayed either blue or green light emission.
Key Laboratory of Fine Chemical Engineering of Jiangsu Province, Jiangsu Polytechnic University, Changzhou 213164, China
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, 199 Renai Road, Suzhou 215123, China
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, 199 Renai Road, Suzhou 215123, China
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, 199 Renai Road, Suzhou 215123, China
Key Laboratory of Fine Chemical Engineering of Jiangsu Province, Jiangsu Polytechnic University, Changzhou 213164, China
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, 199 Renai Road, Suzhou 215123, China