Optical ridge waveguide using calcium barium niobate (CBN) on silicon substrate for the first time is designed, fabricated and characterized for future integrated electro-optic devices. To obtain single-mode propagation, the CBN thin strip is designed to be surrounded by thick silicon dioxide layer forming a ridge waveguide. Deposition of CBN film on profiled silicon dioxide introduces spatial separation which solves the CBN etching problem. Fabrication, edge polishing and near-field mode profile measurement of the waveguide are carried out. The measurement is in good agreement with the simulation and an exact loss as low as 2.15dB/cm was obtained for the fabricated waveguide.