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Supramolecular cyclodextrin polyrotaxane (PR) has attracted much attention due to their unique flexible properties. In this work, the reducible PR-based cationic block copolymer (SS-PR) was prepared via ATRP of DMAEMA based on the self-assembled pseudo-PR. A series of pseudo-comb polycations (SS-PR-pDM) with different molecular weights were subsequently produced via two-step ATRP of DMAEMA by using...
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