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Trichosporin-B-VIa (TS-B-VIa) has a Pro 14 -kinked helical structure which is considered to be important for the formation of peptaibol-type ion-channels in lipid bilayer membranes. TS-B-VIa and its analog [Aib 14 ]TS-B-VIa with Pro → Aib substitution at position 14, resulting in a straight helical structure, were tested for ion-channel-forming activity in planar lipid bilayer...
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