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A series of LiFe1−xMnxPO4/C composites (x=0, 0.1, 0.3, 0.5, 1) are synthesized via an ion exchange method, utilizing LiOH·H2O, FeSO4·7H2O, MnSO4·H2O, Na3PO4·12H2O, and H3PO4 as the raw materials, citric acid as the carbon source, and reductant, and H2O as the solvent. The composites containing Mn have larger lattice parameters compared to pure LiFeMnPO4/C, due to the larger ionic size of Mn2+ compared...
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