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The validity of the law of mass action in its simplest form (using only the molar concentration) was examined for the case of the binding of counterions to polyions in mixed solutions of a polyelectrolyte and a simple +1:−1 salt at 25°C. The study was made for a polyelectrolyte with a linear charge density ξ=1.8 and monovalent counterions; both the counterions from the original polyelectrolyte as...
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