ZnS quantum dots of size ∼3nm are prepared at 303K using ZnSO 4 and Na 2 S 2 O 3 precursors with thioglycerol as stabilizing agent. Cd 2+ doped ZnS were prepared by varying doping concentration from 1 to 8 wt.%. ZnS quantum dots were mixed with CdS quantum dots of size ∼4nm in the 3:1, 2:1, 1:1, 1:2, 1:3 and 1:4M ratio. The nanoparticles were characterized by UV–vis, photoluminescence (PL), XRD and high-resolution TEM measurements. The XRD pattern, high-resolution TEM image and SAED pattern reveal that the nanoparticles are in well-crystallized cubic phase. The band gap of ZnS has increased from the bulk value 3.7 to 4.11eV showing quantum size effect. Excitonic transition is observed at 274nm in UV absorption and PL emission at 411nm. Doping with Cd 2+ red-shifts both UV and PL spectral bands and enhances the PL band of ZnS nanoparticles. Mixing CdS and ZnS quantum dots in different molar ratios shows red-shift of the band edge in the CdS/ZnS hybrid system. In the 1:1 hybrid system of CdS/ZnS nanoparticles, PL band is red-shifted and the intensity is almost doubled with respect to that of CdS nanoparticles.