By conducting combustion synthesis in high-gravity field, the solidified TiC–TiB 2 with a series of TiB 2 mole content were prepared through adjusting the mole ratio of C and B elements in combustion system. XRD, FESEM and EDS results showed that with increasing TiB 2 mole content, the matrix of TiC–TiB 2 composite ceramics transformed a number of fine TiB 2 platelets from the TiC spherical grains, and fine-grained even ultrafine-grained microstructures were achieved in solidified TiC–50%TiB 2 due to the coupled quasi-eutectic growth under rapid solidification of the ceramic. Properties showed that relative density, Vickers hardness and flexural strength of TiC–50%TiB 2 simultaneously reached the maximum values of 98.7%, 21.5±1.5GPa and 860±35 MPa, whereas the maximum fracture toughness of 13.5±1.5MPam 0.5 was achieved in TiC–66.7%TiB 2 . FESEM fractography analyses of the solidified ceramics indicated that the highest flexural strength achieved in TiC–50%TiB 2 benefits from not only the lowest content of Al 2 O 3 inclusions and Cr–W–Ti borides, but also the achievements of fine-grained microstructure in the near-full-density ceramic and high fracture toughness contributed from a intensive coupled mechanism of crack deflection, crack-bridging and pull-out by a large number of fine TiB 2 platelets.