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The adsorption of NO2 on oxidized TiO2 surface, under dark condition at 296K, has been investigated by in-situ transmission Fourier Transform Infrared Spectroscopy (trans-FTIR) as a function of time. It enabled the determination of detailed NO2 reactive adsorption mechanisms on TiO2. It was evidenced that, as soon as NO2 molecules adsorb on TiO2 surface it dimerize to adsorbed N2O4 species. The strongly...
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