In this work, silver-coated carbon fabric composites have been successfully fabricated via a simple and universal electroless plating method. The microstructures of the composites were characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM), respectively. Glucose was employed as an environment-friendly reducing reagent. It was found that the reaction temperatures and the dosages of glucose played important roles for the formation of excellent silver coatings. The carbon fabric with a compact and continuous silver coating exhibited excellent conductivity, and the optimal volume resistivity could reach 8.99×10−4Ω·cm. Such composites would have potential applications in electromagnetic shielding fields.