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The yellow colour of silver hyponitrite is attributed to an LMCT band at λ max =419nm. Solid Ag 2 N 2 O 2 and its suspensions in water or acetonitrile are light sensitive. LMCT excitation leads to a photolysis according to the equation Ag 2 N 2 O 2 →2Ag+2NO. In the presence of air and water, NO is finally converted to HNO 2 .
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