We report the photocurrent response in a double barrier structure with quantum dots–quantum well inserted in central well. When this quantum dots–quantum well hybrid heterostructure is biased beyond +1 or −1V, the photocurrent response manifests itself as a step-like enhancement, increasing linearly with the light intensity. Most probably, at proper bias condition, the pulling down of the X minimum of GaAs at the outgoing interface of the emitter barrier by the photovoltaic effect in GaAs QW will initiate the Γ–X–X tunneling at much lower bias as compared with that in the dark. That gives rise to the observed photocurrent response.