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A set of vanadium phosphorous oxide (VPO) catalysts, mainly consisting of (VO)2P2O7, VO(PO3)2 or VOPO4·2H2O bulk crystalline phases, has been investigated for the oxidative dehydrogenation (ODH) of ethane to ethylene, a key potential reaction for a sustainable industrial and socioeconomic development. The catalytic performance on these VPO catalysts has been explained on the basis of the main crystalline...
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