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Monoclinic bismuth vanadate nanoparticles (nan-BiVO4) have been used for the selective photo-oxidation of benzyl alcohols (13 examples) to benzaldehydes under visible light irradiation using dioxygen as oxidant. Illumination with a blue LED (λmax=470nm) gave yields more than 30 times greater than bulk BiVO4 with >99% selectivity for several cases. Photo-oxidation of PhCH2OH/PhCD2OH isotopomers...
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