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This study demonstrates that the deactivation of the highly acidic PtH-MFI catalyst in the reaction of benzene alkylation with ethane in ethylbenzene (EB) proceeds in two modes. The first mode corresponds to the selective deactivation of the Pt sites, which are highly active in the hydrogenolysis reactions. This deactivation occurs during the first ∼4h of the catalyst operation and results in the...
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