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The role of surface structure and defects in the oxidative coupling of methane (OCM) was studied over magnesium oxide as a model catalyst. Pure, nano-structured MgO catalysts with varying primary particle size, shape and specific surface area were prepared by sol–gel synthesis, oxidation of metallic magnesium, and hydrothermal post treatments. The initial activity of MgO in the OCM reaction is clearly...
The M1 phase of MoVNbTeOx mixed metal oxide is one of the most attractive catalysts for the oxidative dehydrogenation of ethane (ODHE). This work presents the performance of pure-phase M1/CeO2 nanocomposite catalysts in the ODHE process. Nanosized CeO2 is successfully added to pure-phase M1 catalysts by physical mixing and by a sol–gel method, so that M1/CeO2 nanocomposites with different CeO2 particle...
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