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The effect of chlorine, introduced as trichloroethylene, on the CO hydrogenation activity at atmospheric pressure of an alumina-supported cobalt was studied by operando diffuse reflectance FT-IR spectroscopy (DRIFTS). The IR signal of CO(ads) could be essentially decomposed into only three bands, whether chlorine was present or not. Chlorine induced a strong and partly reversible poisoning. A major...
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