Novel chiral dinuclear complexes of Δ,Δ-[Ni2II((R)-Hsalbn)((R)-salbn)(MeCN)2](ClO4)·2MeCN (1) and Λ,Λ-[Fe2III((R)-salbn)2(OMe)2]·Et2O·H2O (2) ((R)-H 2 salbn=N,N′-disalicylidene-(R)-1,1′-binaphthyl-2,2′-diaminate) were prepared. X-ray crystal structure analyses revealed that both complexes crystallized in chiral space groups of P2 1 2 1 2 1 and P4 1 2 1 2, respectively. In 1, two Ni(II) ions with Δ configuration are bridged by phenoxo groups of (R)-salbn, while in 2 μ 2 -methoxo ions bridge two Fe(III) ions leading to the Λ absolute configuration. Dc magnetic susceptibility measurements suggested antiferromagnetic interactions operative in 1 and 2.