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Since the phase diagram for (Fe,Al)-bearing MgSiO 3 compositions at the P–T conditions of the core–mantle boundary remains ambiguous, we investigated the Fe distribution among the silicate perovskite (Pv) and post-perovskite (PPv) polymorphs using tandem synchrotron analyses of X-ray diffraction and X-ray absorption spectroscopy. We performed measurements at the Fe K-edge of the partitioning...
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