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In the present study, the potential for products other than CaCl 2 to be formed during HCl absorption was studied to shed light on the mechanisms of limestone chlorination. Experiments of different durations were made with a thermogravimetric apparatus, and the crystalline reaction products were identified by X-ray diffractometry (XRD). In the experiments, absorption products with Cl/Ca molar...
In the present work, the objective was to elaborate the chemistry of limestone and HCl in hot flue gases, especially under conditions that are typical of fluidised bed combustors. The effects of temperature, absorbent quality and particle size as well as gas atmosphere on the absorption reactions of HCl have been investigated, as have the products of chlorination. In addition, special emphasis was...
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