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In this contribution, we describe fundamental electronic structures and spin–charge–orbital orderings of 5d transition-metal compounds. By reviewing photoemission spectroscopy studies on CuIr2S4, IrTe2, Cs2Au2Br6, and AuTe2, we discuss the difference between the t2g and eg systems with respect to the spin–orbit splitting versus the Jahn–Teller splitting. In contrast to the Ir oxides with Mott-Hubbard...
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