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The spin-state transition is an interesting phenomenon in perovskite materials. Using the first-principles DFT method and LSDA+U calculations, we have fulfilled a detailed investigation on the structural and magnetic ground states of strongly correlated perovskites, BiCoO3, LaCoO3 and their corresponding alloys Bi1−xLaxCoO3 (BLCO). We have found that the structural stability of this alloy between...
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