We propose a vector mode conversion approach based on tilted fiber Bragg grating (TFBG) written in ring-core fiber with effective separation of eigenmodes. The mode coupling properties of TFBG are numerically investigated. It is shown that under the constraint of phase matching, the conversion of high-order vector modes could be achieved at specific wavelengths. Moreover, the polarization of incident light and tilt angle of TFBG play critical roles in mode coupling process. The proposed TFBG provides an efficient method to realize high-order vector mode conversion, and it shows great potential for fibers based OAM beam generation and fiber lasers with vortex beams output.