Starting from a commercial slurry of high purity α-Al 2 O 3 , freeze-dried powders, cast, filter-pressed or cold isostatically pressed samples were produced. Resulting powders or green bodies showing different particles packing were densified by spark plasma sintering (SPS) to obtain transparent polycrystalline α-Al 2 O 3 . Microstructure and real in-line transmittance (RIT) after SPS were dependent on the particles packing quality. Avoiding large agglomerates, narrowing the pore size distribution, reducing the most-frequent pore size (D mode ) and avoiding macroscopic heterogeneities within the green bodies enabled high RIT values to be achieved in the visible and near-infrared spectrum. However, a limit was achieved in the preparation of green bodies for which reducing the D mode had no more influence on the optical behaviour of samples sintered by SPS. Finally, pure α-Al 2 O 3 samples presenting a high RIT 640nm value of 53% were produced from all the green bodies obtained by the following techniques: filter-pressing, slip casting and cold isostatic pressing.